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Regio- and Stereoselectivity of Ene Reactions: The Dimerization of Bicyclic 1,3-Fused 2-(Trimethylsilyl)cycloprop-1-enes

✍ Scribed by Ko Chou Chen; Wen Chieh Wang; Mei-Yun Chen; Wei-Cheng Chen; Ming-Chieh Her; Gon-Ann Lee


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
148 KB
Volume
2007
Category
Article
ISSN
1434-193X

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Regio- and Stereoselective Ene and Tande
✍ Giuseppe Capozzi; Marco Fragai; Stefano Menichetti; Cristina Nativi πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 300 KB πŸ‘ 1 views

2,4-Dioxopentane-3-thione 1a reacts as an enophile with ethers or allenes as ene counterparts, the formation of the thiophilic adduct is followed by a fast cycloaddition reaction various allyl derivatives affording thiophilic ene adducts as single regioisomers with high (E) stereoselectivity. Using