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ChemInform Abstract: A Novel Regio- and Stereoselective Hydrochlorination Reaction of Acetylenic Selenides; Highly Stereoselective Synthesis of (Z)-1-Chloro-1-seleno-1-enes and Stereodefined Selenoenynes.

โœ Scribed by Aiming Sun; Xian Huang


Publisher
John Wiley and Sons
Year
2001
Weight
28 KB
Volume
32
Category
Article
ISSN
0931-7597

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## Abstract The palladiumโ€catalyzed haloallylation of alkynes (I) in dichloromethane leads stereoselectively to (E)โ€dihalodienes (III), whereas (Z)โ€isomers (IV) are readily obtained by the same reaction in acetic acid in the presence of lithium halides.