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Regio- and stereoselective synthesis of highly functionalized vinyl ethers via coiodination of acetylenic ketones

✍ Scribed by Xie, Meihua; Zhang, Jitan; Ning, Peng; Zhang, Zhannan; Liu, Xing; Wang, Linbo

Book ID
121675592
Publisher
Elsevier Science
Year
2014
Tongue
French
Weight
485 KB
Volume
55
Category
Article
ISSN
0040-4039

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Mn-cnolam are easily and quandtattvciy abtakd under mild mt&io~~ (THF. -1OaC to rt. Ih) by tmument C# ketones with tmmatic Mn-ami&.s such as Ph(Me)NMnZ. They allow to prepare 2 siiyl en01 ethers ami 2 emi esters in hi (kinetic product: 2 99%. ZIE: 9317 to 1001 d h yitlds and with an excdent regio-an