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Regio- and stereoselective synthesis of 2-amino-1-hydroxy-2-aryl ethylphosphonic esters

✍ Scribed by Henri-Jean Cristau; Jean-Luc Pirat*; Marcin Drag; Pawel Kafarski

Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
66 KB
Volume
41
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES

ChemInform Abstract: Regio- and Stereose
ChemInform Abstract: Regio- and Stereoselective Synthesis of 2-Amino-1-hydroxy-2-aryl Ethylphosphonic Esters.
✍ Henri-Jean Cristau; Jean-Luc Pirat; Marcin Drag; Pawel Kafarski πŸ“‚ Article πŸ“… 2001 πŸ› John Wiley and Sons βš– 34 KB πŸ‘ 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v

Stereoselective synthesis of 2-amino-1-h
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A highly stereoselective synthesis of 2-amino-l-hydroxy-3-phenylpropylphosphonic acid was achieved by simple addition of diethyl phosphite to enantiomeric N-blocked phenylalanlnals. These compouds exhibit sit, nificant herbicidal activity.

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The title compounds were stereoselectively synthesized via a semi-benzilic Favorskii rearrangement of 3-aryl-and 3-alkyl-2,2-dichlorocyclobutanols, obtained by stereoselective reduction of the corresponding cyclobutanones. This synthetic pathway, starting from the synthesis of 3-substituted-2,2-dich