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Regio- and stereoselective photodimerization of anthracene derivatives included by cyclodextrins

✍ Scribed by Takashi Tamaki; Tomokuni Kokubu; Kunihiro Ichimura


Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
861 KB
Volume
43
Category
Article
ISSN
0040-4020

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✦ Synopsis


The photodimeri2ation of anthracene derivatives such as 2anthracenesulfonate or 2-anthracenecarboxylate in aqueous solution was found to proceed regio-and stereoselectively in the presence of E-CyD and y-f&D, respectively.

These reaction selectivities were explained in terms of specific inclusion of these compaunds into CyDs.


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## Abstract magnified image Asymmetric 1,3‐dipolar cycloadditions of chiral nitrones to 1‐propene‐1,3‐sultone (**1**) were investigated. Chiral nitrones **6a‐e** reacted with sultone **1** in toluene at 90 Β°C for 24‐36 h to give the corresponding isoxazolidines in moderate yields with high regiose