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Enantiodifferentiating photoisomerization of cyclooctene included and sensitized by benzoate modified β-cyclodextrin derivatives: switching of product chirality by solvent

✍ Scribed by Guangxun Li; Zhizhong Wang; Runhua Lu; Zhuo Tang


Publisher
Elsevier Science
Year
2011
Tongue
French
Weight
661 KB
Volume
52
Category
Article
ISSN
0040-4039

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By using homochiral mesoporous POST-1 (Scheme 1) as an inherently chiral sensitizing host, supramolecular enantiodifferentiating photoisomerizations of (Z)-cyclooctene (1Z) were performed for the first time to examine the sensitizing ability of the chiral nanopores, walls of which are decorated with