Sialic acids',\* are well known as constituents of glycoproteins and glycolipids of cell membranes, and they play a role in biological recognition. It is also known that naturally occurring sialo compounds contain sialic acids in a-glycosidic linkage, except for CMP-N-acetylneuraminic acid. Therefo
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Regio- and stereo-selective intermolecular interceptions of a conjugated N-acylhydrazonium ion
โ Scribed by Phillip M. Cowley; Richard J. Stoodley; Glynn Mitchell
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- French
- Weight
- 227 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0040-4039
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A pseudodisaccharide, a 5-0-Q?-D-mannopyranosyl)-2-deoxystreptamine derivative, was obtained preferentially when 2,3&tri-O-ally&6-0-benzyl-a-D-mannopyranosyl chloride (1) was used as the glycosyl donor for coupling with I ,3-di-~-~nzyloxyc~bonyl-Z-d~xyst~ptamine (2) usmg silver t&late as a promoter