Reformatsky Reaction in Water: Evidence for a Radical Chain Process
โ Scribed by Bieber, Lothar W.; Malvestiti, Ivani; Storch, Elisabeth C.
- Book ID
- 120416058
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 84 KB
- Volume
- 62
- Category
- Article
- ISSN
- 0022-3263
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๐ SIMILAR VOLUMES
Although the Reformatsky reaction' has been extensively investigated, there are still many unoertain points about its mechanism,2 and particularly on whether the formation of diastereoisomeric hydroxyesters is under kinetic or thermodynamic control, \*1~2a~b~3 indirect evidence in favor or against e
Atmospheric pressure rate coefficients for the loss of HO 2 , CH 3 O 2 , and C 2 H 5 O 2 radicals to the wall of a " Teflon tube have been measured. In dry air, they are 2.8 ฯฎ 0.2 s ฯช1 1 4 for HO 2 and 0.8 ฯฎ 0.1 s ฯช1 for both CH 3 O 2 and C 2 H 5 O 2 radicals. The rate coefficient for HO 2 loss inc