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Reexamination of orbital interactions in Diels–Alder reactions

✍ Scribed by Atsushi Ogawa; Hiroshi Fujimoto

Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
133 KB
Volume
43
Category
Article
ISSN
0040-4039

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✦ Synopsis

An application of the perturbation theory to the [4+2] addition of butadiene has demonstrated that the effect of secondary orbital interactions should be much less significant than has been assumed within the frontier orbital scheme. This has been confirmed by a numerical analysis with respect to the endo transition state of the Diels-Alder reaction between butadiene and maleic anhydride.

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