The effect of Lewis acid catalysts on the mechanism of Diels-Alder reactions is studied using the MINDO/3 method. It is found that they tend to increase the two-step character of the process through a more important participation of the charge-transfer configuration.
✦ LIBER ✦
ChemInform Abstract: A Three-Center Orbital Interaction in the Diels—Alder Reactions Catalyzed by Lewis Acids.
✍ Scribed by Shinichi Yamabe; Tsutomu Minato
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 23 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0931-7597
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