A rigid linear array of beads in a Newtonian fluid is used to model a rod-like macromolecule in a dilute solution. Following the work of Kotaka, an expression is obtained relating the intrinsic viscosity to the velocity gradient. Computed results are compared with the experimental results of Str6mbe
โฆ LIBER โฆ
Reentrant transition in the shear viscosity of dilute rigid-rod dispersions
โ Scribed by Kobayashi, Hideki; Yamamoto, Ryoichi
- Book ID
- 121856294
- Publisher
- The American Physical Society
- Year
- 2011
- Tongue
- English
- Weight
- 668 KB
- Volume
- 84
- Category
- Article
- ISSN
- 1063-651X
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## Abstract A method for estimating the zero shear rate viscosity for dilute solutions of rigid macromolecules with complex configurations is proposed; this method is based on the macromolecular kinetic theory of Curtiss, Bird, and Hassager. Macromolecular models constructed from a collection of sp
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