𝔖 Bobbio Scriptorium
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Redundant Pathways of Sunscreen Biosynthesis in a Cyanobacterium

✍ Scribed by Dr. Edward Spence; Dr. Walter C. Dunlap; Prof. J. Malcolm Shick; Dr. Paul F. Long

Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
456 KB
Volume
13
Category
Article
ISSN
1439-4227

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A stereoselective chlorination of a methyl group and the preference of cleavage of nonactivated primary C-H bonds in one of the methyl groups with respect to a weaker tertiary C-H bond in the course of the biosynthesis of barbamide point to a surprising, new mechanism of "biohalogenation" (see schem