Reduktive Oligomerisierung von 1,2-Di-tert-butyl-1,1,2,2-tetrachlordisilan: Das Tetracyclo[3.3.0.02,7.03,6]octasilan- und das Tricyclo[2.2.0.02,5]hexasilan-System
β Scribed by Dr. Yoshio Kabe; Mutsumi Kuroda; Dr. Yoshihiro Honda; Dr. Osamu Yamashita; Dr. Takeshi Kawase; Prof. Dr. Satoru Masamune
- Publisher
- John Wiley and Sons
- Year
- 1988
- Tongue
- English
- Weight
- 344 KB
- Volume
- 100
- Category
- Article
- ISSN
- 0044-8249
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π SIMILAR VOLUMES
2(C10&. H:O sind diamagnetisch. Diese Befunde deuten auf die Existenz einer Mo-Mo-Bindung in 2 hin. Die Bindungsverhaltnisse der Metall-Metall-Bindung in 2 lassen sich analog zu denen in Komplexen des Typs [X,M(p-X)3MX3]'0'30 mit lokaler D,,-Symmetrie diskutieren["I, wenn man beriicksichtigt, da0 de
bidentate coordination of unsaturated complex fragments. To our knowledge the only other bridge-forming S4 ligands are found in copper([) polysulfide clusters, in which two copper centers are each bridged by a terminal member of the S, chain.r31 The formation of 1 proceeds via several intermediates