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REDUCTIVE SYNTHESIS OF α,α-DIMETHYLPHENETHYLAMINE

✍ Scribed by Fritz-Hans Marquardt


Book ID
114880765
Publisher
John Wiley and Sons
Year
1973
Tongue
English
Weight
271 KB
Volume
214
Category
Article
ISSN
0890-6564

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Practical synthesis of ynolate anions: n
✍ Mitsuru Shindo; Ryoko Koretsune; Wakako Yokota; Kotaro Itoh; Kozo Shishido 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 64 KB

Reductive lithiation of a,a-dibromo esters using lithium naphthalenide afforded ester dianions leading to ynolate anions in good yields. Naphthalene-catalyzed reductive lithiation was also accomplished. This is a convenient, economical and practical method for the preparation of ynolate anions.