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Reductive methylenation of ketones to give allyl alcohols

โœ Scribed by B. A. Trofimov; A. I. Mikhaleva; O. V. Petrova; M. V. Sigalov


Book ID
112487386
Publisher
Springer
Year
1985
Tongue
English
Weight
56 KB
Volume
34
Category
Article
ISSN
1573-9171

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Cathodic coupling of ketones with trimet
โœ Shigenori Kashimura; Manabu Ishifune; Yoshihiro Murai; Tatsuya Shono ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 225 KB

Cathodic coupling of ketones with 3-(trimethylsilyl)allyl alcohols has been found to give trimethylsilyl substituted 1,3-diols with high diastereoselectivity, whereas that with 2-(trimethylsilyl)allyl alcohols afforded homoallylic alcohols through the Peterson elimination of intermediately formed tr