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Communications- Hydrazine Reduction of α, β-Epoxy Ketones to Allylic Alcohols

✍ Scribed by Wharton, P; Bohlen, D


Book ID
117990735
Publisher
American Chemical Society
Year
1961
Tongue
English
Weight
238 KB
Volume
26
Category
Article
ISSN
0022-3263

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Highly stereoselective synthesis of eryt
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Erythro-a, B-epoxy alcohols were prepared in high stereoselectivity by zinc borohydride reduction of the corresponding a, B-epoxy ketones regardless of the substituents on the epoxide ring. Epoxidation of the ally1 alcohols (L) with tert-butyl hydroperoxide catalyzed by VO(acac)2 was reported to giv