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Reductive elimination of aryl carboxylates from acyl(aryloxy)nickel(II) and -palladium(II) complexes

✍ Scribed by Komiya, Sanshiro.; Akai, Yasushi.; Tanaka, Kohkichi.; Yamamoto, Takakazu.; Yamamoto, Akio.

Book ID: 127189335
Publisher: American Chemical Society
Year: 1985
Tongue: English
Weight: 883 KB
Volume: 4
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om00125a033

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Anions of 1,3-dicarbonyl compounds are some of the most common ligands in transition-metal chemistry. [1, 2] They typically bind in an h 2 -O,O fashion, [3] have delocalized charge, and donate electron density more weakly to a metal center than alkyls or alkoxides. They are usually supporting ligand