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Reductive desulfurization of sultones prepared via intramolecular diels-alder reaction of a furan-containing vinylsulfonate

โœ Scribed by Peter Metz; Eva Cramer


Publisher
Elsevier Science
Year
1993
Tongue
French
Weight
236 KB
Volume
34
Category
Article
ISSN
0040-4039

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Preparation of enantiopure sultams by in
โœ Viktor O. Rogatchov; Heiko Bernsmann; Pia Schwab; Roland Frรถhlich; Birgit Wibbel ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 102 KB

Enantiomerically pure dand g-sultams have been prepared by intramolecular [4+2] cycloaddition of N-1-phenylethyl substituted vinylsulfonamides with purely thermal activation and under high pressure. An optimized procedure for reductive debenzylation of the resultant d-sultams is also reported.