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Reductive dehalogenations by alkali metals and sodium naphthalenide. Capture of solvent-derived intermediates

✍ Scribed by Smith, James G.; Ho, Issac.


Book ID
127303234
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
745 KB
Volume
37
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES


Stereochemistry of reduction of cyclic k
✍ Graziano Castaldi; Giulio Perdoncin; Claudio Giordano; Francesco Minisci πŸ“‚ Article πŸ“… 1983 πŸ› Elsevier Science 🌐 French βš– 243 KB

Surmary: An opposite stereoselectivity is observed in the r&cticn of 3d-hydroxy-5j%7-oxo-cholaic acid by alkali notals and by sodiun dithicnite, ccntraty to the results reported' with other cyclic or bicyclic ketones. An electrartrznsfer mechanism follmed by coupling of the ketyl radical with SOI is