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Reductive decyanization of α-amino nitriles with NaBH4 a new synthetic approach to isoquinoline- and indole-alkaloids

✍ Scribed by Shun-ichi Yamada; Hiroshi Akimoto

Publisher
Elsevier Science
Year
1969
Tongue
French
Weight
202 KB
Volume
10
Category
Article
ISSN
0040-4039

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The reaction of thioesters with nitriles
The reaction of thioesters with nitriles. A new synthetic approach to the preparation of substituted 4-alkylthio- and 4-arylthiopyrimidine derivatives
✍ Antonio Herrera; Roberto Martı́nez-Alvarez; Pedro Ramiro 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 138 KB

Alkyl and S-aryl thioesters react with nitriles in the presence of triflic anhydride to form substituted 4-alkylthio-and 4-arylthiopyrimidines. However, when methyl thiocyanate is used as nitrile, dithioimidocarbonates are formed. A mechanism to explain these differences is postulated.