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Reductive decomplexation of biscobalthexacarbonyl acetylenes into olefins

✍ Scribed by Seijiro Hosokawa; Minoru Isobe

Book ID
104259020
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
238 KB
Volume
39
Category
Article
ISSN
0040-4039

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✦ Synopsis

The decomplexation of acetylene biscobalthexacarbonyl complexes can usually be achieved under oxidative condition. We had found other reductive conditions with endo-cyclic complexes, and recently other reductive conditions with both endo-and exo-cyclic complexes using either tributyltin hydride or triethylsilane. The original acetylene derivatives were transformed selectively either into the corresponding cis olefins or cis-vinylsilanes.

πŸ“œ SIMILAR VOLUMES

ChemInform Abstract: Reductive Decomplex
ChemInform Abstract: Reductive Decomplexation of Biscobalthexacarbonyl Acetylenes into Olefins.
✍ S. HOSOKAWA; M. ISOBE πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 38 KB

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