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ChemInform Abstract: Reductive Decomplexation of Biscobalthexacarbonyl Acetylenes into Olefins.

✍ Scribed by S. HOSOKAWA; M. ISOBE

Book ID
101869957
Publisher
John Wiley and Sons
Year
2010
Weight
38 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable via the β€œReferences” option.

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The decomplexation of acetylene biscobalthexacarbonyl complexes can usually be achieved under oxidative condition. We had found other reductive conditions with endo-cyclic complexes, and recently other reductive conditions with both endo-and exo-cyclic complexes using either tributyltin hydride or t

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## Hydrosilylation of Acetylenes with Catalytic Biscobalthexacarbonyl Complex and Its Application to Heteroconjugate Addition Methodology. -Carbohydrate derived acetylenes (I) and (V) undergo efficient hydrosilylation in the presence of catalytic biscobalthexacarbonyl complexes. The phenylthioace