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Reductive deamination of aromatic amines with nitric oxide (NO)

✍ Scribed by Takashi Itoh; Yûji Matsuya; Kazuhiro Nagata; Akio Ohsawa

Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
214 KB
Volume
37
Category
Article
ISSN
0040-4039

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Reaction of Nitric Oxide with Amines. -NO and NO/O2, respectively, are found to be useful reagents for the aromatization of Hantzsch dihydropyridines (→ (II)) and deamination of aromatic amines (→ (VI)). -

Reaction of amides with nitric oxide (NO
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✍ Takashi Itoh; Kazuhiro Nagata; Yûji Matsuya; Michiko Miyazaki; Akio Ohsawa 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 215 KB

Amides were allowed to react with nitric oxide in aprotic and non-ethereal solvents to give the corresponding N-nittoso derivatives. The reaction was accelerated by addition of oxygen. The solvent effect revealed that the reaction did not proceed in the presence of protic media.