## Abstract The __tert__βbutoxyl radical, generated by the aqueous Ti^III^/TBHP system, abstracts an H atom from alcoholic cosolvents (EtOH, __i__PrOH), leading to Ξ±βhydroxyalkyl radicals thatreduce aromatic aldehydes to the corresponding 1,2βdiols. The reactivities observed are explained by resona
β¦ LIBER β¦
Reductive Coupling of Aromatic Aldehydes Promoted by an Aqueous TiCl3/tBuOOH System in Alcoholic Cosolvents.
β Scribed by Angelo Clerici; Cosimina Greco; Walter Panzeri; Nadia Pastori; Carlo Punta; Ombretta Porta
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 26 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
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