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Facile Reduction of Aromatic Aldehydes, Ketones, Diketones and Oxo Aldehydes to Alcohols by an Aqueous TiCl3/NH3 System: Selectivity and Scope.

✍ Scribed by Angelo Clerici; Nadia Pastori; Ombretta Porta


Publisher
John Wiley and Sons
Year
2003
Weight
353 KB
Volume
34
Category
Article
ISSN
0931-7597

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Reductive Coupling of Aromatic Aldehydes
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

Reductive Coupling of Aromatic Aldehydes
✍ Angelo Clerici; Cosimina Greco; Walter Panzeri; Nadia Pastori; Carlo Punta; Ombr πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 130 KB

## Abstract The __tert__‐butoxyl radical, generated by the aqueous Ti^III^/TBHP system, abstracts an H atom from alcoholic cosolvents (EtOH, __i__PrOH), leading to α‐hydroxyalkyl radicals thatreduce aromatic aldehydes to the corresponding 1,2‐diols. The reactivities observed are explained by resona