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Reductive coupling of aralkyl halides by vanadium(II)

โœ Scribed by Cooper, T. A.


Book ID
127010163
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
590 KB
Volume
95
Category
Article
ISSN
0002-7863

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Reduction of aralkyl halides with dibora
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In continuation of the work in a previously published paper, 1 we wish to 2 report the effective reduction of aralkyl halides with diborane in nitromethane.

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An efficient electro-reductive coupling of aryl bromides and iodides into biaryls has been performed by the electrolysis with Pd(O)and/or Pd(II)-catalysts in a DMF-Et4NOTs-(Pb cathode) system. I-Bromoand 2-bromopyridines were also converted into the corresponding bipyridyls, respectively. Electra-r