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Reductive alkylation of .beta.-alkanolamines with carbonyl compounds and sodium borohydride

✍ Scribed by Saavedra, Joseph E.


Book ID
120552865
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
412 KB
Volume
50
Category
Article
ISSN
0022-3263

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The reduction of ketones and some esters by sodium borohydride is dramatically accelerated by uv irradiation. The reaction seems to proceed from the (n, .rr\*) excited state of the carbonyl compound. The photocatalytic effect is dependent on the solvent polarity and substituents on aromatic carboxyl