Reductive Activation of tripod Metal Compounds: Preparative Application
✍ Scribed by Jürgen Mautz; Gottfried Huttner
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 580 KB
- Volume
- 2008
- Category
- Article
- ISSN
- 1434-1948
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Treatment of the tripod compounds tripodCoCl 2 (1), and tri-podCoCl (2), [tripod = CH 3 C(CH 2 PPh 2 ) 3 ] in THF solution under argon atmosphere with strong reducing agents such as KC 8 leads to the generation of reactive species. While the dinitrogen compound tripodCo(N 2 )Cotripod (3), which is f
We found that lanthanum metal was an excellent agent for the reduction of carbonyl compounds in the presence of a catalytic amount of iodine. When carbonyl compounds were treated with lanthanum metal in the presence of a catalytic amount of iodine, the reductive coupling of the carbonyl compounds pr
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