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Reduction of Unsaturated Steroids with Deuterium: Distribution of Isotope and Mechanism 1

โœ Scribed by Fukushima, David K.; Gallagher, T. F.


Book ID
127083052
Publisher
American Chemical Society
Year
1955
Tongue
English
Weight
528 KB
Volume
77
Category
Article
ISSN
0002-7863

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The mechanism of the reduction of ฮฑ,ฮฒ-un
โœ Ian Midgley; Carl Djerassi ๐Ÿ“‚ Article ๐Ÿ“… 1972 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 130 KB

Caglioti and coworkers have shown that certain a&unsaturated ketones react with excess diborane, and after hydrolysis of the organoborane intermediate with acetic anhydride, good yields of an alkene are obtained. 192 The reaction undoubtedly follows the course depicted in the Scheme: Scheme