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Reduction of tertiary halides to hydrocarbons with sodium borohydride in sulfolane

โœ Scribed by Hutchins, Robert O.; Bertsch, Robert J.; Hoke, David

Book ID
126240659
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
310 KB
Volume
36
Category
Article
ISSN
0022-3263

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๐Ÿ“œ SIMILAR VOLUMES

Sodium borohydride in dimethyl sulfoxide
Sodium borohydride in dimethyl sulfoxide or sulfolane. Convenient systems for selective reductions of primary, secondary and certain tertiary halides and tosylates
โœ Robert O. Hutchins; David Hoke; Joseph Keogh; David Koharski ๐Ÿ“‚ Article ๐Ÿ“… 1969 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 191 KB

The use of various metal hydrides as selective reducing agents has attracted a considerable amount of interest in recent years (2). It occurred to us that one unexplored possibility in this area might be to employ the relatively mild reducing agent sodium borohydride in SNP rate enhancing, polar, ap