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Reduction of some iridium(iv) halogenocomplexes by benzene-1,4-diols in aqueous perchloric acid

✍ Scribed by D.F.C. Morris; T.J. Ritter


Book ID
116013356
Publisher
Elsevier Science
Year
1979
Weight
673 KB
Volume
65
Category
Article
ISSN
0022-5088

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Reduction of hexachloroiridate (IV) by b
✍ D. F. C. Morris; T. J. Ritter 📂 Article 📅 1979 🏛 John Wiley and Sons 🌐 English ⚖ 305 KB

## Abstract The kinetics of the reaction between benzene‐1,2‐diol(catechol) and hexachloroiridate (IV) have been measured in aqueous acidic perchlorate solutions by the stopped‐flow method. The reaction is second order overall, and first order in each reactant. A reverse reaction also occurs, but i