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Kinetics and mechanism of oxidation of 1,1′-biphenyl-4,4′-diol by tris(1,10-phenanthroline)iron(III) and its derivatives in aqueous acidic perchlorate media

✍ Scribed by Ezio Pelizzetti; Edoardo Mentasti

Book ID
115974902
Publisher
Elsevier Science
Year
1977
Weight
322 KB
Volume
39
Category
Article
ISSN
0022-1902

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Kinetics and mechanism of oxidation of q
Kinetics and mechanism of oxidation of quinols by tris(1,10-phenanthroline) iron(III) complexes in aqueous acidic perchlorate media
✍ Edoardo Mentasti; Ezio Pelizzetti 📂 Article 📅 1977 🏛 John Wiley and Sons 🌐 English ⚖ 399 KB

## Abstract The kinetics of oxidation of several substituted quinols by a series of Tris(1,10‐phenanthroline)iron(III) complexes has been investigated with a stopped‐flow technique at 6.0 and 20.0°C. The reactions were found to be first order on both reactants and independent of acidity. The second