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Reduction of polychloromethanes andα,α,α,β-tetrachloroalkanes with silicon hydrides in the presence of Fe(CO)5OR H2PtCI·6H2O

✍ Scribed by E. Ts. Chukovskaya; N. A. Kuz'mina

Book ID
112432440
Publisher
Springer
Year
1969
Tongue
English
Weight
209 KB
Volume
18
Category
Article
ISSN
1573-9171

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📜 SIMILAR VOLUMES

Regioselective Addition of tert -BuN⋮C t
Regioselective Addition of tert -BuN⋮C to the α Carbon Atom of the Allenyl Ligand in [Fe 2 (CO) 6 (μ-PPh 2 ){μ-η 1 :η 2α,β -(H)C α C β C γ H 2 }]: Formation of [Fe 2 (CO) 6 (μ-PPh 2 ){μ-η 1 :η 1 -( tert -BuN⋮C)CCCH 3 }] and [Fe 2 (CO) 6 (μ-PPh 2 )(μ-η 1 :η 2 -{ tert -BuNHC(O)CH 2 }CCH 2 )] via Competitive 1,3-Hydrogen Migration and Hydrolysis of the Reactive Allene-Bridged Intermediate [Fe 2 (CO) 6 (μ-PPh 2 ){μ-η 1 :η 1 -( tert -BuNC)HCCCH 2 }]
✍ Doherty, Simon; Hogarth, Graeme; Waugh, Mark; Scanlan, Tom H.; Clegg, William; E 📂 Article 📅 1999 🏛 American Chemical Society 🌐 English ⚖ 138 KB
Competitive Nucleophilic Attack at CO an
Competitive Nucleophilic Attack at CO and C β of the Allenyl Group in [Fe 2 (CO) 6 (μ-PPh 2 )(μ-η 1 :η 2 -(H)C α C β C γ H 2 )]. X-ray Crystal Structures of [Fe 2 (CO) 5 (μ-PPh 2 )(μ-η 1 ( O ):η 1 ( C ):η 2 ( C )- {OC(N t BuH)CH 2 }CCH 2 )]·0.5C 6 H 14 and [Fe 2 (CO) 6 (μ-PPh 2 )(μ-η 1 :η 1 -CH 2 C(NCyH)CH 2 ]·MeCN
✍ Doherty, Simon; Elsegood, Mark R. J.; Clegg, William; Waugh, Mark 📂 Article 📅 1996 🏛 American Chemical Society 🌐 English ⚖ 197 KB