Reduction of olefins on solid support using diimide
✍ Scribed by Patrick Lacombe; Bastien Castagner; Yves Gareau; Réjean Ruel
- Book ID
- 104259842
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- French
- Weight
- 110 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
The reduction of solid supported olefinic substrate using diimide is described. The diimide, prepared from sulfonylhydrazide, was found to efficiently reduce the olefinic substrates. Typically, the reaction proceeds in over 90% yield to afford the reduction product cleanly after cleavage from the Wang resin.
📜 SIMILAR VOLUMES
## Abstract A versatile reducing agent, diimide, can be generated efficiently by the aerobic oxidation of hydrazine with neutral and cationic synthetic flavin catalysts **1** and **2**. This technique provides a convenient and safe method for the aerobic reduction of olefins, which proceeds with 1
## Abstract Acrylonitrile–butadiene rubber (NBR) latex was hydrogenated using diimide in the presence of selenium catalysts under an oxygen atmosphere. The process has been optimized and is extremely effective in the hydrogenation of NBR latex, with more than 3350 carbon–carbon double bonds reduced
## Abstract A wide variety of olefins is reduced by diimide which is generated in situ by the aerobic oxidation of hydrazine in the presence of flavin catalysts (I) or (II).