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Reduction of O-acyl oximes

โœ Scribed by Daniel D. Sternbach; W.C.L. Jamison

Book ID
104234229
Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
192 KB
Volume
22
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

found to be excellent reducing reagents for

During the course of some synthetic work we needed a method for obtaining 0-acyl hydroxylamines.

Scanning the literature revealed that few general methods for the formation of this species were available, therefore we decided to explore some new routes.

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โœ Barbry, Didier; Champagne, Philippe ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› Taylor and Francis Group ๐ŸŒ English โš– 177 KB

O-acyl derivatives of aldoximes and ketoximes are reduced in good yields to the corresponding amines with sodium borohydride-iodine system. Recent paper1 on the reduction of aromatic oximes with borohydride system prompts us to report our results on the transformation of oximes to amines. This rea