Reduction of nitrobenzene to aniline with carbon monoxide and water
✍ Scribed by Skupińska, Jadwiga ;Smółka, Grzegorz
- Publisher
- Springer
- Year
- 1998
- Tongue
- English
- Weight
- 196 KB
- Volume
- 63
- Category
- Article
- ISSN
- 0133-1736
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📜 SIMILAR VOLUMES
The influence of aniline (PhNH,) on the reductive carbonylation of nitrobenzene (PhNO,) by carbon monoxide and an excess of methanol, catalyzed by (w/w % with respect to PhNO,): sulfur (IO>, sodium methoxide (2). ammonium metavanadate (0. I), at 423 + 2 K and starting pressure of CO 13 MPa (298 K) w
Nitroarenes were readily transformed to aminoarenes in excellent yields under mild conditions with carbon monoxide and water in the presence of a platinum catalyst. Triethylamine, SnC14 and PPh3 are essential for the high catalytic activity. Nitroarenes are reduced chemoselectively by this procedure