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Reduction of N -Acyl-2,3-dihydro-4-pyridones to N -Acyl-4-piperidones Using Zinc/Acetic Acid

โœ Scribed by Comins, Daniel L.; Brooks, Clinton A.; Ingalls, Charles L.

Book ID
127334036
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
26 KB
Volume
66
Category
Article
ISSN
0022-3263

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ChemInform Abstract: C-3 Acetoxylation o
ChemInform Abstract: C-3 Acetoxylation of N-Acyl-2,3-dihydro-4-pyridones.
โœ D. L. COMINS; D. A. STOLZE; P. THAKKER; C. L. MCARDLE ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 28 KB ๐Ÿ‘ 2 views

C-3 Acetoxylation of N-Acyl-2,3-dihydro-4-pyridones. -Stereoselective C-3 acetoxylation of various N-acyldihydropyridones (I) is achieved under mild conditions using lead tetraacetate. The analogous reaction of the indolizidinone (IV) to the cis product proceeds with considerably lower yield.