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Reduction of hydrazines to amines with aqueous solution of titanium(iii) trichloride

โœ Scribed by Zhang, Yan; Tang, Qiang; Luo, Meiming

Book ID
120508831
Publisher
Royal Society of Chemistry
Year
2011
Tongue
English
Weight
232 KB
Volume
9
Category
Article
ISSN
1477-0520

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๐Ÿ“œ SIMILAR VOLUMES

Reduction of hydrazines to amines with a
Reduction of hydrazines to amines with aqueous solution of titanium(iii) trichloride
โœ Zhang, Yan; Tang, Qiang; Luo, Meiming ๐Ÿ“‚ Article ๐Ÿ“… 2011 ๐Ÿ› Royal Society of Chemistry ๐ŸŒ English โš– 232 KB

N-N bond cleavage in hydrazines is widely used in the preparation of amines and thus occupies a significant place in organic synthesis. In this paper, we report a new method for the reductive cleavage of N-N bonds in hydrazines by commercially available and cheap aqueous titanium(III) trichloride. T

ChemInform Abstract: Reduction of Hydraz
ChemInform Abstract: Reduction of Hydrazines to Amines with Aqueous Solution of Titanium(III) Trichloride.
โœ Yan Zhang; Qiang Tang; Meiming Luo ๐Ÿ“‚ Article ๐Ÿ“… 2011 ๐Ÿ› John Wiley and Sons โš– 47 KB

## Abstract The new method is compatible with C=C, Bnโ€”N, Cbzโ€”Nโ€ and Acโ€”N bonds and proceeds under a broad pH range from acidic to neutral and basic conditions to afford the corresponding primary and secondary amines.