Amine N-oxides have been observed to be reduced by titanium(II1) chloride. To study this reaction, 24 model amine N-oxides were reacted with titanium(II1) chloride. The products of these reactions were shown by melting (boiling) points, mixed melting points, derivatives, refractive indices, infrared
β¦ LIBER β¦
ChemInform Abstract: Reduction of Hydrazines to Amines with Aqueous Solution of Titanium(III) Trichloride.
β Scribed by Yan Zhang; Qiang Tang; Meiming Luo
- Publisher
- John Wiley and Sons
- Year
- 2011
- Weight
- 47 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
The new method is compatible with C=C, BnβN, CbzβNβ and AcβN bonds and proceeds under a broad pH range from acidic to neutral and basic conditions to afford the corresponding primary and secondary amines.
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