The reactions of e aq Ϫ , CH 2 OH⅐, (CH 3 ) 2 COH⅐, O H ⅐ and N 3 ⅐ radicals with peroxo ؒϪ CO , 2 terpyridine complexes of Cu(II), Zn(II), and Cu(II)-Zn(II) in aqueous solution were investigated by pulse radiolysis. The primary products from the reduction and oxidation of the macrocyclic complexes
✦ LIBER ✦
Reduction of hexaazacyclophane complexes of Co(II) and Cu(II) by z.rad;CH2OH and esol−; A pulse radiolysis study
✍ Scribed by J. Vargas; G. Ferraudi; J. Canale; J. Costamagna
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 719 KB
- Volume
- 226
- Category
- Article
- ISSN
- 0020-1693
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Redox reactions of peroxo terpyridine co
✍
Sudhir Kapoor; M. S. Sastry
📂
Article
📅
2000
🏛
John Wiley and Sons
🌐
English
⚖ 123 KB
👁 2 views
A vacuum DSC study of Ni(II), Cu(II) and
✍
K.J. Cavell; J.O. Hill; R.J. Magee
📂
Article
📅
1979
🏛
Elsevier Science
🌐
English
⚖ 229 KB
Synthesis, characterization of a novel c
✍
Giuseppe Arena; Annalinda Contino; Elisa Longo; Domenico Sciotto; Carmelo Sgarla
📂
Article
📅
2003
🏛
Elsevier Science
🌐
French
⚖ 300 KB
Mechanism of Reduction of 2,2-Dibromomet
✍
Elisabetha Shandalov; Israel Zilbermann; Eric Maimon; Yeoshua Nahmani; Haim Cohe
📂
Article
📅
2003
🏛
John Wiley and Sons
🌐
English
⚖ 130 KB
A Pulse Radiolysis Study of Catalytic Su
✍
Stéphanie Durot; François Lambert; Jean-Philippe Renault; Clotilde Policar
📂
Article
📅
2005
🏛
John Wiley and Sons
🌐
English
⚖ 102 KB
Kinetics and mechanism of H2O2 decomposi
✍
Mohamed A. Salem; Ibrahim A. Salem; Ali H. Gemeay
📂
Article
📅
1994
🏛
John Wiley and Sons
🌐
English
⚖ 356 KB
👁 1 views
## Abstract The kinetics of the H~2~O~2~ decomposition by Cu(II)‐, Co(II)‐, and Fe(III)‐amine complexes supported on the surface of silica‐alumina (25% Al~2~O~3~) catalyst have been investigated. The decomposition process proceeded with first‐order kinetics for the substrate concentration. With cop