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Mechanism of Reduction of 2,2-Dibromomethyl-1,3-propanediol by NiI-Tetraazamacrocyclic Complexes in Aqueous Solution − A Pulse Radiolysis and Electrochemical Study

✍ Scribed by Elisabetha Shandalov; Israel Zilbermann; Eric Maimon; Yeoshua Nahmani; Haim Cohen; Eilon Adar; Dan Meyerstein


Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
130 KB
Volume
2003
Category
Article
ISSN
1434-1948

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The Redox Chemistry of (N1-[3-(2-aminoet
✍ Yael Albo; Eric Maimon; Israel Zilbermann; Magal Saphier; Haim Cohen; Dan Meyers 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 172 KB

## Abstract The ligand (N^1^‐[3‐(2‐aminoethylimino)‐1,1‐dimethylbutyl]ethane‐1,2‐diamine), L^1^, induces a high ligand field on the central Ni^II^ ion. Thus it is relatively easy to oxidize(Ni^II^L^1^)^2+^. However, the kinetic stability of the Ni^III^L^1^ complexes is considerably lower than that