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Reduction of elemental selenium by samarium diiodide: Selective synthesis of diorganyl selenides and diselenides

✍ Scribed by Masahito Sekiguchi; Hiromichi Tanaka; Noriaki Takami; Akiya Ogawa; Ilhyong Ryu; Noboru Sonoda

Publisher: John Wiley and Sons
Year: 1991
Tongue: English
Weight: 351 KB
Volume: 2
Category: Article
ISSN: 1042-7163
DOI: 10.1002/hc.520020310

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✦ Synopsis

The reduction of elemental selenium by samarium diiodide led to selective formation o f selenolate anion species (Se2 ~ and St.5 -), the alkylation of which provided dialkyl selenides and diselenides, respectively, in excellent yields.

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