Selective synthesis of organic sulfides
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Akiya Ogawa; Noriaki Takami; Masahito Sekiguchi; Noboru Sonoda; Toshikazu Hirao
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Article
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1998
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John Wiley and Sons
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English
โ 128 KB
๐ 2 views
Elemental sulfur can be reduced to the corresponding thiolate anion species (S โซื2โฌ and ) se- ## โซื2โฌ S 2 lectively by samarium diiodide in the presence and absence of HMPA, respectively. The subsequent alkylation of the thiolate anion species provides a useful synthetic route to dialkyl sulfides