Reduction of ce(iv) by carboxylic acid in sulphate medium: part I. monocarboxylic acids
β Scribed by Nabila M. Guindy; S. Hanafi; S.S. Anis
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 223 KB
- Volume
- 92
- Category
- Article
- ISSN
- 0040-6031
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The kinetics of the reduction of hexachloroiridate(IV) by benzyl alcohol (PhCH 2 OH), some substituted benzyl alcohols (XC 6 H 4 CH 2 OH, where X = NO 2 , Cl and OMe), and benzhydrol (Ph 2 CHOH) to give benzaldehyde, the corresponding substituted benzaldehydes and benzophenone, respectively, were in
Silver(1) catalyzed oxidation of aspartic acid by cerium(1V) was studied in acid perchlorate medium. The stoichiometry of the reaction is represented by the eq. (i) Dimeric cerium(IV) species has been indicated and employed in calculations of monomeric cerium(IV) species concentrations. The reactio