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Reduction of alkyl-(4-hydrqxy-3,5-di-t-butylphenyl)-ketones with sodium borohydride

✍ Scribed by A. A. Volod'kin; N. V. Portnykh; V. V. Ershov

Book ID
112435978
Publisher
Springer
Year
1968
Tongue
English
Weight
169 KB
Volume
17
Category
Article
ISSN
1573-9171

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## Abstract The reduction of condensed imides 1 with sodium borohydride proceeds regio‐ and stereoselectively to yield the hydroxylactams 2, 3 and 4. AM1 calculations of the reactants and products reveal that the regiochemistry of the reductions seems to be controlled by both electronic and steric