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Reduction of aldehydes and ketones by sodium dithionite

โœ Scribed by De Vries, Johannes G.; Kellogg, Richard M.


Book ID
120651864
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
560 KB
Volume
45
Category
Article
ISSN
0022-3263

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Stereochemistry of reduction of cyclic k
โœ Graziano Castaldi; Giulio Perdoncin; Claudio Giordano; Francesco Minisci ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 243 KB

Surmary: An opposite stereoselectivity is observed in the r&cticn of 3d-hydroxy-5j%7-oxo-cholaic acid by alkali notals and by sodiun dithicnite, ccntraty to the results reported' with other cyclic or bicyclic ketones. An electrartrznsfer mechanism follmed by coupling of the ketyl radical with SOI is