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Reduction of a Diester to a Hydroxyester by Lithium Aluminum Hydride. Application to the Construction of Rings

✍ Scribed by Bachmann, W. E.; Dreiding, Andre S.

Book ID
127118326
Publisher
American Chemical Society
Year
1949
Tongue
English
Weight
263 KB
Volume
71
Category
Article
ISSN
0002-7863

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Reduction of a Diester to a Hydroxyester
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✍ Bachmann, W. E.; Dreiding, Andre S. πŸ“‚ Article πŸ“… 1949 πŸ› American Chemical Society 🌐 English βš– 263 KB

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Lithium aluminum hydride, in the presence of a small amount of silica gel, has been found to be a versatile and highly selective reagent for reduction of various ketoesters to the corresponding hydroxyesters in fair yields. Recently we reported a series of new synthetic reactions l-7) with the use