Reduction and Isomerization of cis - and trans -1,2-Vinylenebis(diphenylphosphines) and Disulfides
β Scribed by Aguiar, Adam M.; Daigle, Donald.
- Book ID
- 126088436
- Publisher
- American Chemical Society
- Year
- 1964
- Tongue
- English
- Weight
- 266 KB
- Volume
- 86
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
The photolysis of SOz at 3712 A in the presence of the 1,2-dichloroethylenes has been investigated at 22Β°C. The data are consistent with the SOz( 3B1) photosensitized isomerization of the 1,2-dichloroethylene isomer. A kinetic treatment of the initial quantum yield data was consistent with the forma
Quantum yield measurements for the S02(3B1) photosensitized isomerization of cis-1,2-diflu%roethylene have been made at 3712 A and 22Β°C. The ## [ S O ~] / [ C ~T -C ~F ~H Z ] ratio was varied from 47.4 to 455 and the quantum yield measurements over this variation of concentration ratios were consi