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A Stereospecific Route to trans - and cis -1,2-Vinylenebis(diphenylphosphine)

✍ Scribed by Aguiar, Adam M.; Daigle, Donald.


Book ID
127000129
Publisher
American Chemical Society
Year
1964
Tongue
English
Weight
274 KB
Volume
86
Category
Article
ISSN
0002-7863

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A short, stereospecific route to chiral
✍ E.J Corey; Po-wai Yuen πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 French βš– 230 KB

An efficient six-step stereospecific synthesis of trans-2,Gdiphenylquinuclidine (1) is described together with an effective resolution of 1 into pure enantiomers. A key step in the synthesis is a highly efficient, catalyzed Diels-Alder reaction. Although the quinuclidine ring is an important struct