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Redox Reactions in Strontium Iron Phosphates: Synthesis, Structures, and Characterization of Sr 9 Fe(PO 4 ) 7 and Sr 9 FeD(PO 4 ) 7

โœ Scribed by Belik, Alexei A.; Izumi, Fujio; Azuma, Masaki; Kamiyama, Takashi; Oikawa, Kenichi; Pokholok, Konstantin V.; Lazoryak, Bogdan I.; Takano, Mikio


Book ID
123617297
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
270 KB
Volume
17
Category
Article
ISSN
0897-4756

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New phosphates, Sr1.9Cu4.1(PO4)4, Sr2Cu(PO4)2, and Sr9.1Cu1.4(PO4)7, were found in the Cu3(PO4)2+Sr3(PO4)2 system at 9003C under air. Sr1.9Cu4.1(PO4)4 crystallizes in an orthorhombic system with a โ€ซุโ€ฌ 15.3695(7) A > , b โ€ซุโ€ฌ 10.3652(4) A > , and c โ€ซุโ€ฌ 7.9425(4) A > . Crystal structures of Sr9.1Cu1.4(